FY2022 Results on Background Monitoring for Mercury in Atmosphere and Precipitation, and other Elements in Aerosols

Ministry of the Environment, Government of Japan (MOEJ), has been conducting background monitoring for atmospheric mercury at Cape Hedo in Okinawa Prefecture (hereinafter referred to as Cape Hedo) and at Oga Peninsula in Akita Prefecture (hereinafter referred to as Oga), where direct effect from local emission sources is minimal.

The results of the survey in Fiscal Year (FY) 2022 (April 1st, 2022, through March 31st, 2023) indicated that mercury concentrations in atmosphere and precipitation at Cape Hedo and Oga were well below the national guideline values, and these values did not deviate significantly from those of the past survey results.

1. Overview of the Survey

MOEJ has been monitoring background concentrations of atmospheric mercury, namely Gaseous Elemental Mercury (GEM), Gaseous Oxidized Mercury (GOM), Particle Bound Mercury (PBM), and mercury deposited with precipitation at Cape Hedo and Oga.

In addition, 17 hazardous elements and six index elements were monitored at Cape Hedo to understand the source, fate and transportation of atmospheric mercury.

2. Summary of Survey Result

(1) Atmospheric Mercury Concentration

Annual mean concentrations of the sum of all mercury forms in the atmosphere in FY2022 were 1.6 ng/m3 at Cape Hedo and 1.5 ng/m3 at Oga, both of which were well below the guideline values for hazardous air pollutants to reduce health risks (i.e. 40 ng/m3 as annual mean value).
At both sites, GEM accounted for a large portion of mercury in the atmosphere (see Tables 4 and 6 of the Attached Document).
At Cape Hedo, annual mean concentrations of speciated mercury and total atmospheric mercury have remained at a constant level since FY2013 (see Table 1 and the Attached Document Table 5 for detail).

Table 1 Atmospheric mercury concentrations at Cape Hedo (annual mean)

(Unit:ng/m³) [1]

Measured item	FY2013	FY2014	FY2015	FY2016	FY2017	FY2018	FY2019	FY2020	FY2021	FY2022
GEM	1.7	1.7	1.6	1.7	1.6	1.6	1.7	1.7	1.7	1.6
GOM	0.002	0.002	0.001	0.002	0.002	0.002	0.002	0.002	0.001	0.001
PBM	0.004	0.004	0.002	0.003	0.002	0.002	0.002	0.002	0.002	0.002
Total	1.7	1.7	1.7	1.7	1.6	1.6	1.7	1.7	1.7	1.6

[1] The concentrations of mercury and its compounds converted to the amount of mercury are shown. The same applies to Tables 2 and 3.

At Oga, annual mean concentrations of GEM, GOM and total atmospheric mercury have remained at a constant level since FY2014(see Table 2 and Attached Document Table 7 for detail).

Table 2 Atmospheric mercury concentrations at Oga (annual mean)

(Unit: ng/m³)

Measured item	FY2014	FY2015	FY2016	FY2017	FY2018	FY2019	FY2020	FY2021	FY2022
GEM	1.6	1.6	1.6	1.6	1.6	1.5	1.6	1.6	1.5
GOM	0.002	0.003	0002	0.003	0.003	0.002	0.003	0.003	0.003
PBM	0.009	0.009	0.011	0.009	0.008	0.006	0.012	0.006	0.007
Total	1.6	1.6	1.6	1.6	1.6	1.5	1.6	1.6	1.5

Note: FY2014 monitoring program started from August 8, 2014.

(2) Mercury Concentration in Precipitation

The annual mean concentration of mercury in precipitation in FY2022 was 5.4 ng/L at Cape Hedo and 6.2 ng/L at Oga. The concentration at Cape Hedo and Oga were within the range of previous years (see Table 3 and Attached Document Tables 9 and 11 for detail).

Table 3 Mercury concentration in precipitation at Cape Hedo and Oga (annual mean)

(Unit: ng/L)

Monitoring site	FY2016	FY2017	FY2018	FY2019	FY2020	FY2021	FY2022
Cape Hedo	6.6	4.8	3.9	5.6	5.0	5.3	5.4
Oga	6.3	5.7	6.0	6.0	7.9	5.5	6.2

(3) Concentrations of Other Metal Elements in Aerosols

In FY2021, annual mean concentrations of chromium, manganese, nickel, arsenic, cadmium and lead in aerosols at Cape Hedo were 3.9 ng/m3, 2.9 ng/m3, 0.90 ng/m3, 0.51 ng/m3, 0.057 ng/m3 and 1.4 ng/m3, respectively (see Table 4). These concentrations were significantly lower than the guideline values for hazardous air pollutants to reduce health risks, where applicable (guideline values as annual mean: manganese 140 ng/m3, nickel 25 ng/m3 and arsenic 6 ng/m3)..
The annual mean concentration of chromium was the second highest compared to surveys so far. Meanwhile, that of manganese recorded the lowest levels as in 2016, and arsenic, cadmium and lead were the second lowest in the survey period so far.
For nickel, it was within the range of previous years.

Table 4 Metal element concentrations in aerosols at Cape Hedo (annual mean)

(Unit: ng/m³) [2]

Measured item	Guide-line value	FY2012	FY2013	FY2014	FY2015	FY2016	FY2017	FY2018	FY2019	FY2020	FY2021	FY2022
Chromium (Cr)	－	1.3	1.2	1.4	0.69	0.65	0.91	1.8	2.1	4.3	2.5	3.9
Manganese (Mn)	140	7.4	4.9	6.6	3.7	2.9	4.0	4.9	3.7	4.2	3.0	2.9
Nickel (Ni)	25	1.1	1.8	1.5	1.1	0.74	0.98	0.97	0.86	1.0	0.76	0.90
Arsenic (As)	6	0.99	0.98	1.1	0.74	0.73	0.73	0.70	0.66	0.61	0.43	0.51
Cadmium (Cd)	－	0.17	0.19	0.20	0.13	0.13	0.11	0.096	0.083	0.067	0.052	0.057
Lead (Pb)	－	7.3	6.9	6.5	3.4	3.1	2.9	2.7	2.1	1.8	1.3	1.4

[2]The concentrations of each metal and its compounds converted to the amount of each metal are shown.
Note: "Guideline value" denotes the "guideline values for hazardous air pollutants to reduce health risks" of Japan.

3. Future Action

MOEJ will continue this background mercury monitoring survey to contribute to grasp international mercury emissions and global trend of mercury concentration and their impact on the Japanese environment.
Under the supervision of experts, the results of this monitoring will be released on a regular basis.
Furthermore, in order to contribute to the effectiveness evaluation of the Minamata Convention on Mercury, we will widely provide data and disseminate the results of monitoring and share internationally the technical knowledge accumulated to ensure accuracy and precision of measurement.

■ Appendix 1 Outline of monitoring sites

Outline of monitoring sites

Site	Cape Hedo Atmosphere and Aerosol Monitoring Station：CHAAMS
Address	Naganehara 1000, Ginama, Kunigami-son, Kunigami-gun, Okinawa
Location	26.87°N, 128.25°E
Overview	CHAAMS is a monitoring station established and operated by the National Institute for Environmental Studies, Japan, for aerosols and gases monitoring in the atmosphere in order to understand transboundary air pollution. It is located in the north end of the Okinawa Island, where no anthropogenic pollution source of hazardous metals is expected in the surrounding area. Cape Hedo is an optimum location in Japan from which the atmospheric conditions in East Asia could be monitored. Air masses from China, Korea, Japan, and Southeast Asia can be sampled depending on the season.

Site	Oga Peninsula
Address	Izumidai 3-2, Funagawaminato-funagawa, Oga-shi, Akita
Location	39.89°N, 139.85°E
Overview	Oga Peninsula monitoring station was installed adjacently to Funakawa Ambient Air Pollution Monitoring Station operated by Akita Prefecture. It is in the south side of the Oga Peninsula that protrudes into the Sea of Japan. There is no source of mercury in the surrounding area. Therefore, it is suitable for observing background mercury concentration in the northern part of Japan.

map of monitoring sites

■ Appendix 2 Sampling and analytical methods of different forms of mercury and other metal elements in atmosphere

Component	Measurement items		Sampling and analytical methods	Site
Atmosphere	Mercury	Mercury forms (GEM, GOM, PBM)	Continuous measurement with Tekran® mercury speciation system	Cape Hedo Oga
	Particulate matter	17 hazardous elements Be, V, Cr, Mn, Co, Ni, Cu, Zn, As, Se, Cd, Sn, Sb, Ba, Te, Tl, Pb	7 days continuous sampling by using a low-volume sampler and analyzed by ICP/MS	Cape Hedo
	Particulate matter	6 index elements Na, Mg, Al, K, Ca, Fe		Cape Hedo
Precipitation	Hg		Sampling by using an automatic wet-only sampler and analyzed by CVAAS (EPA method 1631, Revision E)	Cape Hedo Oga

Attached Documents

令和4年度大気中水銀バックグラウンド濃度等のモニタリング調査結果について（別添）

FY2022 Results on Background Monitoring for Mercury in Atmosphere and Precipitation, and other Elements in Aerosols (attachment) [PDF 4.0 MB] (in Japanese) (in Japanese)